Preparation of Poly (N-Isopropylacrylamide)-Poly (2-Ethyl-2-Oxazoline) and Their Self-Assembly Properties with Dicarboxylic Acid

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dc.authorscopusid57211338973
dc.authorscopusid6504473814
dc.authorscopusid57195458120
dc.contributor.authorYilmaz Erdogan P.
dc.contributor.authorEmre F.B.
dc.contributor.authorSeçkin T.
dc.date.accessioned2024-08-04T20:03:34Z
dc.date.available2024-08-04T20:03:34Z
dc.date.issued2024
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThis study reports the synthesis of copolymers that contain thermally responsive polymers, namely poly(N-isopropylacrylamide) (PNIPAM) and poly(2-ethyl-2-oxazoline) (PEOX), as well as biodegradable side groups that are water-soluble and capable of hydrogen bonding. The assay aims to produce heat-responsive PNIPAM and PEOX polymers with di-carboxylic acid (DCA) controlled structuring of the resulting pH-sensitive nano-structured polymers. These will be used as a template in the synthesis of inorganic materials. The study demonstrated the impact of pH, salt concentration, and temperature on the polymer/DCA. This fragment describes the functional groups of the thermosensitive polymers PNIPAM and PEOX. These polymers have carboxylic acid functional groups at both ends, are water soluble, and are capable of hydrogen bonding. The structure of these polymers can be recognized with small molecules of DCA in an aqueous solution at different pH, salt concentrations, and temperatures with H-bonds. Additionally, these polymers can be used as templates to synthesize hollow silica polymers. The synthesized monomers and polymers were structurally characterized using Fourier transform infrared spectrophotometer (FT-IR). The resulting structured polymers were identified by scanning electron microscopy and atomic force microscopy (SEM, AFM). UV-VIS spectrophotometer and Differential Scanning Calorimetry (DSC) were used to determine the Lower Critical Solution temperature of the polymers. © 2024, Turkish Chemical Society. All rights reserved.en_US
dc.description.sponsorshipInönü Üniversitesi: BAP 2016-13; Inönü Üniversitesien_US
dc.description.sponsorshipThis work was supported by Inonu University, BAP 2016-13en_US
dc.identifier.doi10.18596/jotcsa.1150117
dc.identifier.endpage824en_US
dc.identifier.issn2149-0120
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85195155241en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage813en_US
dc.identifier.trdizinid1241500en_US
dc.identifier.urihttps://doi.org/10.18596/jotcsa.1150117
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/1241500
dc.identifier.urihttps://hdl.handle.net/11616/91933
dc.identifier.volume11en_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isoenen_US
dc.publisherTurkish Chemical Societyen_US
dc.relation.ispartofJournal of the Turkish Chemical Society, Section A: Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectnano-structured materialen_US
dc.subjectpH-sensitivityen_US
dc.subjectSelf-organizationen_US
dc.subjecttemplateen_US
dc.titlePreparation of Poly (N-Isopropylacrylamide)-Poly (2-Ethyl-2-Oxazoline) and Their Self-Assembly Properties with Dicarboxylic Aciden_US
dc.typeArticleen_US

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